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Apr 01 2018 · Nanocrystalline CuAlO2 was synthesized by mechanical alloying of Cu2O and αAl2O3 powders in the molar ratio of 11 for 20 h in toluene medium with tungsten carbide balls and vials using planetary ball mill The ball milling was carried out at 300 rpm with a ball to powder weight ratio of 101 and then annealed at 1373 K in a platinum crucible